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A new approach to very high lithium salt content quasi-solid state electrolytes for lithium metal batteries using plastic crystals

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journal contribution
posted on 2019-01-01, 00:00 authored by Danah Al-MasriDanah Al-Masri, Ruhamah Yunis, Haijin Zhu, L Jin, P Bruce, A F Hollenkamp, Jenny PringleJenny Pringle
While the high energy density of lithium metal has long been a strong driver for the development of lithium metal batteries, harnessing the full theoretical capacity in a safe, practical device requires significant advances in electrolyte design. The use of quasi-solid state electrolytes can be greatly beneficial for increasing safety, suppressing the growth of lithium dendrites and prolonging cell lifetime. Organic ionic plastic crystals (OIPCs) are a unique class of disordered solid that can support high ionic conductivities and lithium ion mobility. Until recently, OIPCs were used primarily as matrix materials and incorporated only low dopant concentrations of lithium salts. Here we report a very high lithium content electrolyte containing 90 mol% lithium bis(fluorosulfonyl)imide, Li[FSI], combined with 10 mol% of a conductive pyrrolidinium FSI-based OIPC. The resultant quasi-solid state electrolyte achieves a conductivity of 0.24 mS cm-1 at 30 °C, supports stable lithium electrochemistry and has a very good lithium ion transference number of 0.68. Symmetrical Li|Li cell cycling is demonstrated at 0.1 mA cm-2 for 100 hours. This showcases a new approach for designing safer quasi-solid state electrolytes with high lithium content and excellent electrochemical and transport properties.

History

Journal

Journal of materials chemistry A

Volume

7

Issue

44

Pagination

25389 - 25398

Publisher

The Royal Society of Chemistry

Location

Cambridge, Eng.

ISSN

2050-7488

eISSN

2050-7496

Language

eng

Publication classification

C1 Refereed article in a scholarly journal