merenda-assessingthetemporal-2016.pdf (2.17 MB)
Assessing the temporal stability of surface functional groups introduced by plasma treatments on the outer shells of carbon nanotubes
journal contribution
posted on 2016-01-01, 00:00 authored by Andrea Merenda, Elise Des Ligneris, K Sears, Thomas Chaffraix, Kevin Magniez, D Cornu, J A Schütz, Ludovic DumeeLudovic DumeePlasma treatments are emerging as superior efficiency treatment for high surface to volume ratio materials to tune functional group densities and alter crystallinity due to their ability to interact with matter at the nanoscale. The purpose of this study is to assess for the first time the long term stability of surface functional groups introduced across the surface of carbon nanotube materials for a series of oxidative, reductive and neutral plasma treatment conditions. Both plasma duration dose matrix based exposures and time decay experiments, whereby the surface energy of the materials was evaluated periodically over a one-month period, were carried out. Although only few morphological changes across the graphitic planes of the carbon nanotubes were found under the uniform plasma treatment conditions, the time dependence of pertinent work functions, supported by Raman analysis, suggested that the density of polar groups decreased non-linearly over time prior to reaching saturation from 7 days post treatment. This work provides critical considerations on the understanding of the stability of functional groups introduced across high specific surface area nano-materials used for the design of nano-composites, adsorptive or separation systems, or sensing materials and where interfacial interactions are key to the final materials performance.
History
Journal
Scientific reportsVolume
6Article number
31565Pagination
1 - 12Publisher
Nature Publishing GroupLocation
London, Eng.Publisher DOI
eISSN
2045-2322Language
engPublication classification
C Journal article; C1 Refereed article in a scholarly journalCopyright notice
2016, The AuthorsUsage metrics
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