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Catalytic activity of choline modified Fe(III) montmorillonite
journal contribution
posted on 2011-08-01, 00:00 authored by P J Wallis, Will GatesWill Gates, A F Patti, J L ScottA series of mixed-cation organoclays, containing both Fe3+ and choline+ cations, were prepared using montmorillonite and tested for catalytic activity in three Fe3+-mediated reactions: the oxidative coupling of 2-naphthol, coupling of anthrone and a Lewis-acid catalysed indole conjugate addition. Clays with different Fe3+:choline+ ratios were required to achieve maximum catalytic activity in each reaction. For coupling of both 2-naphthol and anthrone, the most effective catalysts, as measured by the turnover frequency (TOF), were mixed Fe3+/choline+ clays of varying ratios, but the catalytic efficiency of Fe3+ montmorillonite in the conjugate addition of indole with methyl vinyl ketone decreased with the addition of choline+. This result could potentially be explained by the effect of choline+ decreasing the accessibility of Lewis acid domains. The results of this study provide proof that it is possible to tune mixed-cation clays with maximum catalytic activity in specific reaction types for specific substrates. Such mixed-cation organoclays offer advantages over traditional clay-based sorbents in environmental remediation applications, as they have the potential to bind organic contaminants selectively, via interaction with surface-exchanged organic cations, and neutralise organic molecules through catalytic exchange cations that are also present on the clay surface.
History
Journal
Applied clay scienceVolume
53Issue
2Pagination
336 - 340Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
0169-1317eISSN
1872-9053Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2010, ElsevierUsage metrics
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montmorilloniteiron trichloride hexahydrateheterogeneous catalysisoxidative couplingconjugate additioncholineScience & TechnologyPhysical SciencesTechnologyChemistry, PhysicalMaterials Science, MultidisciplinaryMineralogyChemistryMaterials ScienceSOCIETY SOURCE CLAYSCHLORINATED PHENOLSBASE-LINEDEHALOGENATIONEXCHANGESORPTION
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