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Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors
journal contribution
posted on 2005-06-30, 00:00 authored by J Adebahr, Maria ForsythMaria Forsyth, D MacFarlaneDimethyl-pyrrolidinum-based salts have been investigated by means of DSC, conductivity, NMR and Raman spectroscopy. The investigation aims to study the effect of the anion on the behaviour of the salt, in terms of plastic properties as well as rotational degrees of freedom of the cation. The materials range from the non-plastic iodide salt to the highly plastic BF4 salt, which flows under its own weight at elevated temperatures. The different rotational and translational motions of the cations, and the difference between rotator and plastic phases are discussed.
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Journal
Electrochimica actaVolume
50Issue
19Pagination
3853 - 3858Publisher
Elsevier Science Pub. Co.Location
New York, N.YPublisher DOI
ISSN
0013-4686eISSN
1873-3859Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2005, Elsevier Ltd.Usage metrics
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