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Effect of organic additives on the cycling performances of lithium metal polymer cells
journal contribution
posted on 2008-04-01, 00:00 authored by J A Choi, S M Eo, D MacFarlane, Maria ForsythMaria Forsyth, E Cha, D W KimGel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of organic additive. Three kinds of organic compounds, thiophene, 3,4-ethylenedioxythiophene and biphenyl, were used as a polymerizable monomeric additive. The organic additives were found to be electrochemically oxidized to form conductive polymer films on the electrode at high potential. By using the gel polymer electrolytes containing different organic additive, lithium metal polymer cells, composed of lithium anode and LiCoO2 cathode, were assembled and their cycling performance evaluated. Adding small amounts of a suitable polymerizable additive to the gel polymer electrolyte was found to reduce the interfacial resistance in the cell during cycling, and it thus exhibited less capacity fade and better high rate performance. Differential scanning calorimetric studies showed that the thermal stability of the fully charged LiCoO2 cathode was improved in the cell containing an organic additive.
History
Journal
Journal of power sourcesVolume
178Issue
2Pagination
832 - 836Publisher
Elsevier SALocation
SwitzerlandPublisher DOI
ISSN
0378-7753eISSN
1873-2755Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2007, Elsevier B.V. All rights reserved.Usage metrics
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No categories selectedKeywords
Conductive polymerCycling performanceElectrochemical oxidationGel polymer electrolyteLithium metal polymer cellOrganic additiveScience & TechnologyPhysical SciencesTechnologyChemistry, PhysicalElectrochemistryEnergy & FuelsMaterials Science, MultidisciplinaryChemistryMaterials ScienceION BATTERIESOVERCHARGE PROTECTIONCATHODE MATERIALSELECTROLYTELIINTERCALATIONCYCLEABILITYDESIGNLIQUIDANODE
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