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Influence of processing route on the alloying behavior, microstructural evolution and thermal stability of CrMoNbTiW refractory high-entropy alloy

journal contribution
posted on 2020-06-29, 00:00 authored by L Raman, G Karthick, K Guruvidyathri, Daniel FabijanicDaniel Fabijanic, S V S Narayana Murty, B S Murty, R S Kottada
Two different processing routes of mechanical alloying followed by the spark plasma sintering (powder metallurgy) and vacuum arc melting (casting route) were employed to understand the role of processing routes on the phase and microstructural evolution in an equiatomic CrMoNbTiW refractory high-entropy alloy. Besides a major BCC solid solution, a small fraction of carbide, σ phase, nitride, and oxide phases were observed in the alloys prepared by the powder metallurgy route in contrast to a single-phase BCC solid solution in the casting route. The milling atmosphere (dry milling in air and Ar) has significantly influenced the phase and microstructural evolution, illustrating the substantial role of contaminants. Good thermal stability of microstructure at high homologous temperatures was shown based on the long-term heat treatment at 1300 °C for 240 h. The phase evolution predictions via Calphad studies were found to be in reasonable agreement with the experimental observations, albeit with some limitations.

History

Journal

Journal of Materials Research

Volume

35

Issue

12

Pagination

1556 - 1571

Publisher

Materials Research Society

Location

Pittsburgh, PA

ISSN

0884-2914

eISSN

2044-5326

Language

eng

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2020, Materials Research Society