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LiI-doped N,N-Dimethyl-Pyrrolidinium iodide, an archetypal rotator-phase ionic conductor
journal contribution
posted on 2005-10-07, 00:00 authored by J Adebahr, A Seeber, D MacFarlane, Maria ForsythMaria ForsythN,N-Dimethyl-pyrrolidinium iodide, and the effect of doping with LiI, has been investigated using DSC, NMR, and impedance spectroscopy. It was found that the addition of a small amount of LiI enhances the ionic conductivity by up to 3 orders of magnitude for this ionic solid. Furthermore, a slight decrease in phase transition onset temperatures, as well as the appearance of a superimposed narrow line in the 1H NMR spectra with dopant, suggest that the LiI facilitates the mobility of the matrix material, possibly by the introduction of vacancies within the lattice. 7Li NMR line width measurements reveal a narrow Li line width, decreasing in width and increasing in intensity with temperature, indicating mobile Li ions.
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Journal
Journal of physical chemistry B : condensed matter, materials, surfaces, interfaces and biophysicalVolume
109Issue
43Pagination
20087 - 20092Publisher
American Chemical SocietyLocation
Washington, D.C.Publisher DOI
ISSN
1520-6106eISSN
1520-5207Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2005, American Chemical SocietyUsage metrics
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