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Lithium-functionalised silica nanoparticles for enhanced ionic conductivity in an organic ionic plastic crystal
journal contribution
posted on 2010-01-01, 00:00 authored by Y Shekibi, Jenny PringleJenny Pringle, J Sun, S Pas, N Rocher, B Clare, A Hill, D MacFarlane, Maria ForsythMaria ForsythAddition of silica nanoparticles functionalised with lithium propane sulfonate to the organic ionic plastic crystal N-ethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide ([C2mpyr][NTf2]) results in a significant increase in ionic conductivity. Analysis of these nanocomposites by impedance spectroscopy, NMR, positron annihilation lifetime spectroscopy (PALS) and Raman spectroscopy suggests that this is the result of higher matrix mobility due to an increase in defect size and concentration. The effect of these functionalised nanoparticles is compared to that previously observed for unfunctionalised nanoparticles in the lithium-doped and pure plastic crystal.
History
Journal
Journal of materials chemistryVolume
20Issue
2Pagination
338 - 344Publisher
Royal Society of ChemistryLocation
Cambridge, EnglandPublisher DOI
ISSN
0959-9428eISSN
1364-5501Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2010, Royal Society of ChemistryUsage metrics
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