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Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

journal contribution
posted on 2003-06-09, 00:00 authored by L M Caldwell, A J Edwards, A F Hill, H Neumann, Madeleine SchultzMadeleine Schultz
The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

History

Journal

Organometallics

Volume

22

Issue

12

Pagination

2531 - 2534

Publisher

ACS Publications

Publisher DOI

ISSN

0276-7333

Language

eng

Publication classification

C Journal article; C1.1 Refereed article in a scholarly journal

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    Research Publications

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    Keywords

    Science & TechnologyPhysical SciencesChemistry, Inorganic & NuclearChemistry, OrganicChemistryCRYSTAL-STRUCTUREORGANIC-SYNTHESISCOMPLEXESACTIVATIONREACTIVITYTHIOETHERMOLECULESALKYNESRHIROrganic ChemistryInorganic Chemistry

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