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Room temperature fast-ion conduction in imidazolium halide salts
journal contribution
posted on 2001-01-01, 00:00 authored by H Every, A Bishop, D MacFarlane, G Orädd, Maria ForsythMaria ForsythFast-ion conduction has been observed in the iodide and bromide salts of 1-methyl-3-ethylimidazolium at ambient temperatures. The melting point of these two compounds is above 350 K and even at 273 K the ionic conductivity in the solid-state is greater than 10−3S cm−1. Cation diffusion coefficients have been measured using fringe field gradient and/or pulse field gradient 1H NMR techniques, which indicated cation diffusion coefficients of the order of 10−10 m2 s−1 in the solid-state. Remarkably, these values are up to an order of magnitude higher than the cation diffusion coefficient in the supercooled liquid at 293 K. The activation energy for diffusion in the solid-state is extremely small, as is typical of solid-state fast-ion conductors and indicates a change in transport mechanism from the melt to the crystal. The inability to detect an 127I signal together with the modelling of the conductivity using the Nernst–Einstein equation suggests that the solid-state conduction is primarily due to cation diffusion. The solid-state fast-ion conduction is most likely related to vacancy diffusion along the cation layers in the crystal. The temperature dependence of the NMR signal intensity indicates that the number of mobile species is increasing with increasing temperature with an activation energy of approximately 20–30 kJ mol−1.
History
Journal
Journal of materials chemistryVolume
11Issue
12Pagination
3031 - 3036Publisher
Royal Society of ChemistryLocation
Cambridge, EnglandPublisher DOI
ISSN
0959-9428eISSN
1364-5501Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2001, Royal Society of ChemistryUsage metrics
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