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Solid state lithium ion conduction in pyrrolidinium imide–lithium imide salt mixtures
journal contribution
posted on 2000-01-01, 00:00 authored by J Huang, Maria ForsythMaria Forsyth, D MacFarlaneThe properties of the binary salt system based on mixtures of methyl ethyl pyrrolidinium bis(trifluoromethane sulfonyl) imide (P12) and lithium bis(trifluoromethane sulfonyl) imide (Li imide) are reported. The lithium containing mixtures were found to be more than two orders of magnitude more conductive than the parent P12 phase and the 33 mol% Li imide systems showed a solid state conductivity around 1×10−4 S/cm at 20°C. This solid state conductivity is believed to take place in plastic crystal phases of the P12 compound.
History
Journal
Solid state ionicsVolume
136-137Pagination
447 - 452Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
0167-2738eISSN
1872-7689Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2000, Elsevier Science B.V.Usage metrics
Keywords
pyrrolidinium bis(trifluoromethane sulfonyl) imidelithium bis(trifluoromethane sulfonyl) imideplastic crystalionic conductorScience & TechnologyPhysical SciencesChemistry, PhysicalPhysics, Condensed MatterChemistryPhysicsELECTRICAL-CONDUCTIVITYMAGNETIC-RESONANCEROTATOR PHASEH-1NMRCondensed Matter Physics
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